PUBLICATIONS

From independent work at Wayne State University

[2009]

64. “Control of Phase in Phosphide Nanoparticles Produced by Metal Nanoparticle Transformation: Fe2P and FeP” Elayaraja , M.; Parashu Ram, K.; Lawes, G.; Brock, S. L. ACS Nano Article published on the web on 4th AUG 2009. http://pubs.acs.org/doi/full/10.1021/nn900574r

63. “Tuning the Optical Band Gap of Quantum Dot Assemblies by Varying Network Density” H. Yu, S. L. Brock. ACS Nano, 2009, 3 (7), 2000-2006. http://pubs.acs.org/doi/pdf/10.1021/nn900456f

62. “Discrete, Dispersible MnAs Nanocrystals from Solution Methods: Phase Control on the Nanoscale and Magnetic Consequences”K. Senevirathne, R. Tackett, P. Kharel, G. Lawes, K. Somaskandan, S. L. Brock. ACS Nano, 2009, 3, 1129-1138. http://pubs.acs.org/doi/pdf/10.1021/nn900194f

61. “Expanding the Repertoire of Chalcogenide Nanocrystal Networks: Ag2Se Gels and Aerogels by Cation Exchange Reactions” Q. Yao, I. U. Arachchige, S. L. Brock. Journal of the American Chemical Society, 2009, 131, 2800–2801. http://pubs.acs.org/doi/pdf/10.1021/ja900042y

[2008]

60. “Effects of Nanoparticle Shape on the Morphology and Properties of Porous CdSe Assemblies (Aerogels)” H. Yu, S. L. Brock. ACS Nano, 2008, 2, 1563-1570. http://pubs.acs.org/doi/pdf/10.1021/nn8002295

59. “Recent Developments in Synthetic Approaches to Transition Metal Phosphide Nanoparticles for Magnetic and Catalytic Applications” K. Senevirathne, S. L. Brock. Journal of Solid State Chemistry (invited contribution to a special issue on Nanoscience), 2008, 181, 1552-1559. doi:10.1016/j.jssc.2008.03.012     

58. “Engineering Strength, Porosity, and Emission Intensity of Nanostructured Networks by Altering the Building-Block Shape” H. Yu, R. Bellair, R. M. Kannan, S. L. Brock. Journal of the American Chemical Society, 2008, 130, 5054-5055. http://pubs.acs.org/doi/pdf/10.1021/ja801212e

57. “Synthesis and Characterization of Fe3P Composite Nanorods Produced by Phosphate Reduction in Anodized Alumina Templates” K. L. Stamm, S. L. Brock. Journal of Alloys and Compounds, 2007, 453, 476-481. http://dx.doi.org/10.1016/j.jallcom.2006.11.175

56. “Synthesis of Discrete and Dispersible MoS2 Nanocrystals” H. Yu, Y. Liu, S. L. Brock. Inorganic Chemistry, 2008, 47 (5), 1428-1434 DOI: 10.1021/ic701020s

55. “On the Feasibility of Phosphide Generation from Phosphate Reduction: The Case of Rh, Ag, and Ir” C. M. Sweeney, K. L. Stamm, S. L. Brock. Journal of Alloys and Compounds, 2008, 448, 122-127.

54. “Temperature Controlled Uptake and Release in PNIPAM-modified Mesoporous Silica Nanoparticles” Y. You, K. K. Kalebaila, S. L. Brock, D. Oupicky. Chemistry of Materials, 2008, 20(10), 3354-2259. DOI: 10.1021/cm703363w

53. “Nanoparticles as Seeds for Organic Crystallization” R. Wang, I. U. Arachchige, S. L. Brock, G. Mao. ACS Symposium Series, 2008. No. 996/Nanoparticles:  Synthesis, Stabilization, Passivation and Functionalization (2008), R. Nagarajan and T. A. Hatton, Eds.

[2007]

52. “Synthesis and Characterization of Discrete Nickel Phosphide Nanoparticles: Effect of Surface Ligation Chemistry on Catalytic Hydrodesulfurization of Thiophene” K. Senevirathne, A. W. Burns, M. E. Bussel, S. L. Brock. Advanced Functional Materials, 2007, 17, 3933-3939. DOI: http://dx.doi.org/10.1002/adfm.200700758

51. “Phase Segregation of MnP in Chalcopyrite Dilute Magnetic Semiconductors: A cautionary Tale” J. A. Aitken, G. Tsoi, L. E. Wenger, S.L. Brock. Chemistry of Materials, 2007, 19, 5272-5278.

50. “Sol-Gel Methods for the Assembly of Quantum-Dot Monoliths I. U. Arachchige” S. L. Brock. Accounts of Chemical Research, 2007, 40, 801-809. http://pubs.acs.org/doi/full/10.1021/ar600028s

49. “Highly Luminescent Quantum Dot Monoliths” I. U. Arachchige, S. L. Brock. Journal of the American Chemical Society, 2007, 129, 1840-1841. DOI: 10.1021/ja066749c

Commentary by BROCK

“Filling a void” Stephanie L. Brock. Science, 2007, 317 (5837), 460-461. DOI: 10.1126/science.1146517

Full Text: http://www.sciencemag.org/cgi/content/full/317/5837/460?ijkey=IzMIZJqpANA6s&keytype=ref&siteid=sci

[2006]

48. “Metal Chalcogenide Gels, Xerogels and Aerogels” S. L. Brock, I. U. Arachchige, K. K. Kalebaila. Comments on Inorganic Chemistry (invited contribution), 2006, 27, 103-126.

47. “CdS aerogels: Effect of concentration and primary particle size on surface area and opto-electronic properties” Journal of Sol-Gel Science and Technology, 2006 ISSN:0928-0707 (Paper) 1573-4846 (Online) DOI: 10.1007/s10971-006-9049-4

46. “Sol-Gel Assembly of CdSe Nanoparticles to form Porous Aerogel Networks” I. U. Arachchige, S. L. Brock. Journal of the American Chemical Society, 2006, 128, 7964-7971.  DOI: 10.1021/ja061561e

45. “From Ribbons to Nanodot Arrays: Nanoparticle Design through Reductive Annealing”  P. Arumugam, S. S. Shinozaki, R. Wang, G. Mao, S. L. Brock. Chemical Communications, 2006, 1121-1123.  DOI: 10.1039/b514595c

44. “Controlled Synthesis of MnP Nanorods:  The Effect of Shape Anisotropy on Magnetization”  K. A. Gregg, S. C. Perera, G. Lawes, S. Shinozaki, S. L. Brock. Chemistry of Materials, 2006, 18, 879-886.  DOI: 10.1021/cm052080h

43. “Synthesis and Characterization of Germanium Sulfide Aerogels”  K. K. Kalebaila, D. G. Georgiev, S. L. Brock.  Journal of  Non-Crystalline Solids, 2006, 352, 232-240. DOI: 10.1016/j.jnoncrysol.2005.11.035

[2005]

42. “Sol-gel Processing of Semiconducting Metal Chalcogenide Xerogels: Influence of Dimensionality on Quantum Confinement Effects in a Nanoparticle Network,”  I. U. Arachchige, J. L. Mohanan, S. L. Brock. Chemistry of Materials, 2005, 17, 6644-6650.  DOI:10.1021/cm0518325

41. “Structure-Property Correlations in Solid Solutions of CuI)8P12-xAsx, 2.4 ≤ x ≤ 6.6”  B. Jayasekera, S. L. Brock, A. Y. H. Lo, R. W. Schurko, G.-A. Nazri. Chemistry, A European Journal, 2005, 11, 3762-3772.  DOI: 10.1002/chem.200400727

40. “Solvothermal Synthesis of Cu3P via Reactions of Amorphous Red Phosphorus and a Variety of Copper Sources,” J. A. Aitken, V. Ganzha-Hazen, S. L. Brock. Journal of Solid State Chemistry, 2005, 178, 970-975.  DOI: 10.1016/j.jssc.2004.10.004

39. "Porous Semiconductor Chalcogenide Aerogels,” J. Mohanan, I. U. Arachchige, S. L. Brock. Science, 2005, 307, 397-401. DOI:10.1126/science.1106525

38. “Isovalent Doping Strategy for Manganese Introduction into III-V Diluted Magnetic Semiconductor Nanoparticles: InP:Mn,”  K. Somaskandan, G. Tsoi, L. E. Wenger, S. L. Brock.  Chemistry of Materials, 2005, 17, 1190-1198.  DOI: 10.1021/cm048796e

[2004]

37.   “Particle-Rod Hybrids: Growth of Arachidic Acid Molecular Rods from Capped Cadmium Selenide Nanoparticles,” D. Chen, R. Wang, I. Arachchige, G. Mao, S. L. Brock.  Journal of the American Chemical Society, 2004, 126, 16290-16291. DOI: 10.1021/ja045011x

36.   “A New Addition to the Aerogel Community: Unsupported CdS Aerogels with Tunable Optical Properties,” J. L. Mohanan, S. L. Brock.  Journal of Non-Crystalline Solids (special issue from the 7th International Symposium on Aerogels), 2004, 350, 1-8. DOI: 10.1016/j.jnoncrysol.2004.05.020

35.   “Liberation of Pnicogen Chains from Cu2P1.8As1.2I2:  Synthesis and Characterization of a New Polymer of P-As,” B. Jayasekera, K. Somaskandan, S. L. Brock.  Inorganic Chemistry, 2004, 43, 6902-6904. DOI: 10.1021/ic0490223

34.   “Chemical Routes for Production of Transition Metal Phosphides on the Nanoscale: Implications for Advanced Magnetic and Catalytic Materials,” S. L. Brock, S. C. Perera, K. L. Stamm.  Chemistry-A European Journal, 2004, 10, 3364-3371 (invited Concepts paper).  DOI: 10.1002/chem..200305775

[2003]

33.   “Synthesis of MnP Nanocrystals by Treatment of Metal Carbonyl Complexes with Phosphines: A New, Versatile Route to Nanoscale Transition Metal Phosphides,” S. C. Perera, G. Tsoi, L. E. Wenger, S. L. Brock.  Journal of the American Chemical Society, 2003, 125, 13960-13961.  DOI: 10.1021/ja038037h

32.   “Application of De-silylation Strategies to the Preparation of Transition Metal Pnictide Nanocrystals:  The Case of FeP,”  S. C. Perera, P. S. Fodor, G. Tsoi, L. Wenger, S. L. Brock.  Chemistry of Materials, 2003, 15, 4034-4038. DOI: 10.1021/cm034443o

31.   “Influence of Synthetic and Processing Parameters on the Surface Area, Speciation, and Particle Formation in Copper Oxide/Silica Aerogel Composites,” J. Mohanan, S. L. Brock.  Chemistry of Materials, 2003, 15, 2567-2576. DOI: 10.1021/cm021741x

30.   “Effect of Precursor Salt on FeP Nanoparticle Formation,” S. C. Perera, S. L. Brock.  Materials Research Society Symposium Proceedings, 2003, 755, DD5.9.1-DD5.9.6.

29.   “Ag Ion-Exchange Reactions of Cu2P3I2 and Cu2P1.8As1.2I2,”  B. Jayasekera, S. L. Brock.  Materials Research Society Symposium Proceedings, 2003, 755, DD6.12.1-DD6.12.6.

28.   “A General Methodology for the Synthesis of Transition Metal Pnictide Nanoparticles from Pnictate Precursors and its Application to Iron-Phosphorus Phases.”  K. L. Stamm, J. C. Garno, G.-y. Liu, S. L. Brock.  Journal of the American Chemical Society, 2003, 125, 4038-4039. DOI: 10.1021/ja028180v

27.   “Towards an Arsenic Analog of Hittorf’s Phosphorus:  Mixed Pnicogen Chains in Cu2P1.8As1.2I2,”  B. Jayasekera, J. A. Aitken, M. J. Heeg, S. L. Brock.  Inorganic Chemistry, 2003, 42, 658-660.  DOI: 10.1021/ic0258936

 

Brock papers from Postdoctoral, Graduate, and Undergraduate work

 26.   “Dynamic Organization of Inorganic Nanoparticles into Periodic Micrometer Scale Patterns,” O. Giraldo, J. P. Durnad, H. Ramanan, K. Laubernds, S. L. Suib, M. Tsapatsis, S. L. Brock, M. Marquez.  Angewandte Chemie International Edition, 2003, 42, 2905-2909.  DOI: 10.1002/anie.200250712

[2002]

25.   “Application of Non-Thermal Atmospheric Pressure AC Plasmas to the Carbon Dioxide Reforming of Methane,” S. L. Brock, T. Shimojo, S. L. Suib, Y. Hayashi, H. Matsumoto.  Research on Chemical Intermediates, 2002, 28, 13-24. DOI: 10.1163/156856702760129465

[2001]

24.   “Tetraalkylammonium Manganese Oxide Gels:  Preparation, Structure, and Ion Exchange Properties,” S. L. Brock; M. Sanabria, J. Nair, S. L. Suib, T. Ressler.  Journal of Physical Chemistry B, 2001, 105, 5404-5410.  DOI: 10.1021/jp003943r

23.   “Synthesis and Characterization of a Nanofibrous Sodium Manganese Oxide with a 2 x 4 Tunnel Structure,”  G.-G. Xia, W. Tong, E. N. Tolentino, N.-G. Duan, S. L. Brock, J.-Y. Wang, S. L. Suib, T. Ressler.  Chemistry of Materials, 2001, 13, 1585-1592.  DOI: 10.1021/cm000777r

[2000]

22.   “Destruction of Freons by the Use of High-Voltage Glow Plasmas,” F.-J. Spiess, X. Chen, S. L. Brock, S. L. Suib, Y. Hayashi, H. Matsumoto.  Journal of Physical Chemistry A, 2000, 104, 11111-11120.  DOI: 10.1021/jp0021190

21.   “Spontaneous Formation of Inorganic Helical Fibers and Rings,” O. Giraldo, M. Marquez, S. L. Brock, S. L. Suib, H. Hillhouse, M. Tsapatsis.  Journal of the American Chemical Society, 2000, 122, 12158-12163.  DOI: 10.1021/ja0018872

20.   “Manganese Oxide Thin Films with Fast Ion-Exchange Properties,” O. Giraldo; S. L. Brock; W. S. Willis; M. Marquez; S. L. Suib; S. Ching.  Journal of the American Chemical Society, 2000, 122, 9330-9331. DOI: 10.1021/ja001860i

19.   “Spontaneous Formation of Inorganic Helices,” O. Giraldo; S. L. Brock; M. Marquez; S. L. Suib; H. Hillhouse; M. Tsapatsis.  Nature, 2000, 405, 38-38.

[1999]

18.   “Particle Size Control and Self-Assembly Processes in Colloids of Nanocrystalline Manganese Oxide,” S. L. Brock, M. Sanabria, S. L. Suib, V. Urban, P. Thiyagarajan and D. I. Potter.  Journal of Physical Chemistry B, 1999, 103, 7416-7428.  DOI: 10.1021/jp991009u

17.   “Structural Studies on Colloidal Tetraalkylammonium Manganese Oxides,” T. Ressler, S. L. Brock, J. Wong, S. L. Suib.  Journal of Synchrotron Radiation, 1999, 6, 728-730.   DOI:10.1107/S0909049599001065

16.   “Multiple-Scattering EXAFS Analysis of Tetraalkylammonium Manganese Oxide Colloids,” T. Ressler, S. L. Brock, J. Wong and S. L. Suib.  Journal of Physical Chemistry B, 1999; 103; 6407-6420. DOI: 10.1021/jp9835972

15.   “Factors Influencing the Decomposition of CO2 in AC Fan-Type Plasma Reactors:  Frequency, Waveform, and Concentration Effects,” S. L. Brock, T. Shimojo, M. Marquez, C. Marun, S. L. Suib.  Journal of Catalysis, 1999, 184, 123-133. DOI: 10.1006/jcat.1999.2440

[1998]

14.   “Plasma Decomposition of CO2 in the Presence of Metal Catalysts,” S. L. Brock, M. Marquez, S. L. Suib, Y. Hayashi and H. Matsumoto.  Journal of Catalysis, 1998, 180, 225-233.  DOI: 10.1006/jcat.1998.2258

13.   “Efficient Catalytic Plasma Activation of CO2, NO, and H2O,” S. L. Suib, S. L. Brock, M. Marquez, J. Luo, H. Matsumoto and Y. Hayashi.  Journal of Physical Chemistry B, 1998, 102, 9661-9666.  DOI: 10.1021/jp9822079

12.   , “A Review of Porous Manganese Oxide Materials,” S. L. Brock, N. Duan, Z.-R. Tian, O. Giraldo, H. Zhou and S. L. Suib.  Chemistry of Materials, 1998, 10, 2619-2628. DOI:10.1021/cm980227h

11.   “Synthesis and Characterization of a New Compound with Alternating MnO22- and Zn2As22- Layers:  Ba2MnZn2As2O2,” T. Ozawa, M. M. Olmstead, S. L. Brock, S. M. Kauzlarich and D. M. Young.  Chemistry of Materials, 1998, 10, 392-396. DOI: 10.1021/cm970554+

 [1996]

10.   "Structure-Property Relationships in a Series of Mixed Layer Pnictide Oxide Compounds:  A2Mn3Pn2O2 (A = Sr, Ba; Pn = P, As, Sb)," S. L. Brock and S. M. Kauzlarich.  Journal of Alloys and Compounds, 1996, 241, 82-88.

9.    "The Magnetic Structures of the Mixed Layer Pnictide Oxide Compounds Sr2Mn3Pn2O2 (Pn = As, Sb)," S. L. Brock, N. P. Raju, J. E. Greedan, and S. M. Kauzlarich.  Journal of Alloys and Compounds, 1996, 237, 9-19.

[1995]

8.    "Unusual Layered Metal Oxides," S. L. Brock and S. M. Kauzlarich.  CHEMTECH, 1995, 25:7, 18-22.

7.    "Pnictide Oxides:  A Unique Class of Compounds," S. L. Brock and S. M. Kauzlarich.  Comments on Inorganic Chemistry, 1995, 17, 213-238.

[1994]

6.    "A2Zn3As2O2 (A = Sr, Ba): A Rare Example of Square Planar Zinc," S. L. Brock, and S. M. Kauzlarich.  Inorganic Chemistry, 1994, 33, 2491-2492. 

5.    "Resistivity and Magnetism of AMn2P2 (A = Sr, Ba):  The Effect of Structure Type on Physical Properties,"  S. L. Brock, J. E. Greedan and S. M. Kauzlarich.  Journal of Solid State Chemistry, 1994, 113, 303-311.

4.    "A Test of the Application of Extended Hückel Calculations to the ThCr2Si2 and CaAl2Si2 Structure Types:  The Case of SrMn2P2 and BaMn2P2," S. L. Brock, J. E. Greedan, and S. M. Kauzlarich.  Journal of Solid State Chemistry, 1994, 109, 416-418. 

3.    "Synthesis and Structure of a New Layered Pnictide Oxide Containing Close Mn-Mn Interactions: Ba2Mn2As2O," S. L. Brock, H. Hope, S. M. Kauzlarich.  Inorganic Chemistry, 1994, 33, 405-406.

[1993]

2.    "Synthesis and Structure of A14AlSb11 (A = Ca, Sr, Ba)," S. L. Brock, L. J. Weston, M. M. Olmstead and S. M. Kauzlarich.  Journal of Solid State Chemistry, 1993, 107, 513-523.

 [1991]

1.    "Oxygen Atom Transfer from a Phosphine Oxide to Tungsten (II) Complexes," S. L. Brock and J. M. Mayer.  Inorganic Chemistry, 1991, 30, 2138-2143.