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47. Hollingsworth, T. S.; Hollingsworth, R. L.; Rosen, T.; Groysman, S. Zinc Bimetallics Suppored by a Xanthene-Bridged Dinucleaing Ligand: Synthesis, Characterization, and Lactide Polymerization Studies. RSC Adv., 2017, 7, 41819-41829.

46. Reed, B. R.; Yousif, M.; Lord, R. L.; McKinnon, M.; Rochford, J.; Groysman, S. Coordination Chemistry and Reactivity of Bis(aldimino)pyridine Nickel Complexes in Four Different Oxidation States. Organometallics, 2017, 36, 582-593

45. Hollingsworth, R. L.; Bheemaraju, A.; Lenca, N.; Lord, R. L.; Groysman, S. Divergent reactivity of a new dinuclear xanthene-bridged bis(iminopyridine) di-nickel complex with alkynes. Dalton Trans., 2017, 46, 5605-5616.

44. Narayanan, R.; McKinnon, M.; Reed, B. R.; Ngo, K. T.; Groysman, S.; Rochford, J. Ambiguous Electrocatalytic CO2 Reduction Behaviour of a Nickel Bis(aldimino)pyridine Pincer Complex. Dalton Trans., 2016, 45, 15285-15289.



43. Bellow, J. A.; Stoian, S. A.; Van Tol, J.; Ozarowski, A.; Lord, R. L.; Groysman, S. Synthesis and Characterization of a Stable High-Valent Cobalt Carbene Complex. J. Am. Chem. Soc., 2016, 138, 5531-5534.


42. Yousif, M.; Cabelof, A. C.; Martin, P. D.; Lord, R. L.; Groysman S. Synthesis of a Mononulcear , Non-Square-Planar Chromium(II) Bis(alkoxide) Complex and its Reactivity Toward Organic Carbonyls and CO2. (Special Issue: New Talent: Americas), Dalton Trans., 2016, 45, 9794-9804.                                                        
                                                                                    See Video which describes the results


41. Beattie, J. W., SantaLucia, D. J., White, D. W., Groysman. S. Oxalate- Templated Synthesis of  Di-Zinc Macrocycles. Inorg. Chim. Acta., 2017, 460, 8-16


40. Bellow, J. A., Yousif, M., Groysman, S. Discrete Complexes of 3d Metals with Monodentate Bulky Alkoxide Ligands and Their Reactivity in Bond Activation and Bond Formation Reactions. Comments Inorg. Chem., 2015, 36, 92-122.

39. Yousif, M., Tjapkes, D.J., Lord, R.L., Groysman, S. Catalytic Formation of Asymmetric Carbodiimides at Mononuclear Chromium (II/IV) Bis(alkoxide) Complexes. Organometallics, 2015, 34, 5119 - 5128.

38. Bellow, J. A., Yousif, M., Fang, D., Kratz, E. G., Cisneros, G. A., Groysman, S. Synthesis and Reactivity of 3d Metal Complexes with the Bulky Alkoxide Ligand [OCtBu2Ph]. Inorg. Chem., 2015, 54, 5624- 5633.

37. Bellow, J. A., Yousif, M., Cabelof, A. C., Lord, R.L., Groysman, S. Reactivity Modes of an Iron Bis(alkoxide) Complex with Aryl Azides: Catalytic Nitrene Coupling vs Formation of Iron(III) Imido Dimers. Organometallics., 2015, 34, 2917-2923.

36. Reed, B.R..; Stoian, S.A.; Lord, R.L.; Groysman S. The Aldimine Effect in Bis(imino)Pyridine Complexes: Non-Planar Nickel(I) Complexes of a Bis(aldimino)pyridine Ligand. Chem. Commun., 2015, 51, 6496-6499.

35. Bheemaraju, A.; Beattie, J.W.; Danylyuk, Y.; Rochford, J.; Groysman S. Synthesis, Structures, and Reactivity of Copper(I) Complexes Supported by a Rigid Dinucleating Ligand. Eur. J. Inorg. Chem., 2014, 34, 5865-5873.

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34. Beattie, J. W.; White, D.S.; Bheemaraju, A.; Martin, P. D.; Groysman, S. Recyclable Chemosensor for Oxalate Based on Bimetallic Complexes of a Dinucleating Bis(iminopyridine) Ligand. Dalton. Trans., 2014, 49, 7979-7986.

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33. Bellow, J. A.; Martin, P. D.; Lord, R. L.; Groysman, S. Reductive Coupling of Azides Mediated by an Iron(II) Bis(alkoxide) Complex, Inorg. Chem., 2013, 52, 12335 -12337.



32. Bellow, J. A.; Fang, D.; Kovacevic, N.; Martin, P. D.; Shearer, J.; Cisneros, G. A.; Groysman, S. Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers, Chem. Eur. J. , 2013, 19, 12225-12228.

31. Bheemaraju A.; Beattie, J. W.; Tabasan, E. G.; Martin, P. D.; Lord, R. L.; and Groysman, S. Steric and Electronic Effects in the Formation of Carbon Disulfide Reactivity of Dinuclear Nickel Complexes Supported by Bis(iminopyridine) Ligands. Organometallics, 2013, 32, 2952-2962.


30. Chambers, M. B.; Groysman, S.; Villigran, D.; Nocera, D. G.; Iron in a Tris(alkoxide) Ligand Enviroment. Inorg. Chem. 2013, 52, 3159-3169.

29. Bheemaraju A.; Beattie, J. W.; Lord, R. L.; Martin, P. D.; and Groysman, S. Carbon Disulfide Binding at Dinuclear and Mononuclear Nickel Complexes Ligated by a Redox-Active Ligand: Iminopyridine Serving as an Accumulator of Redox Equivalents for the Activation of Heteroallenes. Chem. Commun. 2012, 48, 9595-9597.

28. Bheemaraju A.; Lord, R. L.; Müller, P.; and Groysman, S. Difference in the Reactivities of H- and Me-Substituted Dinucleating Bis(iminopyridine) Ligands with Nickel(0). Organometallics 2012, 31, 2120-2123.


27. Groysman, S.; Villagrán, D.; Freedman, D. E.; and Nocera, D. G. Dinitrogen Binding at Vanadium  in the Tris(alkoxide) Ligand Environment. Chem. Commun. 2011, 47, 10242-10244.

26. Groysman, S.; Villagrán, D.; and Nocera, D. G. Pseudo-tetrahedral d0, d1, and d2 Metal-Oxo Cores Within a Tris(alkoxide) Platform. Inorg. Chem. 2010, 49, 10759-10761.

25. Groysman, S.; Majumdar, A.; Zheng, S.-L.; and Holm, R.H. Reactions of Monodithiolene Tungsten(VI) Sulfido Complexes with Copper(I) in Relation to the Structure of the Active Site of Carbon Monoxide Dehydrogenase. Inorg. Chem. 2010, 49, 1082-1089.

24. Groysman, S.; and Holm, R. H. Biomimetic Chemistry of Iron, Nickel, Molybdenum, and Tungsten In Sulfur-Rich Protein Sites. Biochemistry 2009. 48, 2310-2320.

23. Groysman, S., and Holm, R. H. A Series of Mononuclear Quasi-Two-Coordinate Copper(I) Complexes Employing a Sterically Demanding Thiolate Ligand. Inorg. Chem. 2009, 48, 621-627.

22. Groysman, S., Wang, J. - J., Tagore, R., Lee, S. C., and Holm, R. H. A Biomimetic Approach to Oxidized Sites in the Xanthine Oxidoreductase Family: Synthesis and Stereochemistry of Tungsten(VI) Analogue Complexes. J. Am. Chem. Soc. 2008, 130, 12794-12807.

21. Wang, J. - J.; Groysman, S.; Lee, S. C.; and Holm, R. H. Synthesis of Structural Analogues of the Oxidized Sites in the Xanthine Oxidoreductase Enzyme Family. J. Am. Chem. Soc. 2007, 129, 7512-7513.

20. Groysman, S.; and Holm, R. H.. Synthesis and Structures of Bis(dithiolene) Tungsten (IV,VI) Thiolate and  Selenolate  Complexes:   Approaches to the Active Sites of Molybdenum and Tungsten Formate Dehydrogenases. Inorg. Chem. 2007, 46, 4090-4102.

19. Groysman, S.; Sergeeva, E.; Goldberg, I.; and Kol, M. Zinc Complexes of the Amine Mono(phenolate) [NOO2] Ligands: Controlling Coordination Modes by Bulk of Phenolate Substituents. Eur. J. Inorg. Chem. 2006. 2739-2745 (the cover paper of issue No. 14).

18. Kol, M., Segal, S., Groysman, S. 2008. Stereocontrol in the Polymerization of C4+ α-olefin Monomers. In Stereoselective Polymerization with Single-Site Catalysts L. S. Baugh, J.–A. Boca Raton, FL.

17. Gendler, S., Groysman, S., Goldschmidt, Z., Shuster, M., and Kol, M.. Polymerization of 4-methylpentene and Vinylcyclohexane by the Amine Bis(phenolate) Group IV catalysts. J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 1136-1146.

16. Groysman, S.; Sergeeva, E.; Goldberg, I.; and Kol, M. Group IV Complexes of a Tetradentate Amine Mono(phenolate) Ligand: a Second Sidearm Donor Stabilizes Cationic Species. Inorg. Chem. 2005, 44, 8188-8190.

15. Yeori, A.; Groysman, S.; Goldberg, I.; and Kol, M.; 2005.  Diastereoisomerically–Selective Enantiomerically–Pure Titanium Complexes of Chiral Salan Ligands. Inorg. Chem. 2005, 44, 4466-4467.

14. Groysman, S.; Goldberg, I.; Kol, M.; and Goldschmidt, Z. Vanadium(III) and Vanadium(V) Amine Tris(phenolate) Complexes. Inorg. Chem. 2005, 44, 5073-5080.

13. Groysman, S.; Sergeeva, E.; Goldberg, I.; and  Kol. M., Salophan complexes with Group IV Metals. Eur.  J. Inorg. Chem. 2005, 2480-2485.

12. Groysman, S.; Goldberg, I., Kol, M.,  Genizi, E., and Goldshmidt, Z. Exploring Routes to Tantalum (V) Alkyl and Alkylidene Complexes Supported by the Amine Tris(Phenolate) ligands. Adv. Syn. Cat. 2005, 347, 409-415.

11. Groysman, S.; Tshuva, E.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; and Shuster, M. Diverse Structure-Activity Trends in the Amine Bis(phenolate) Titanium Polymerization Catalysts. Organometallics 2004, 23, 5291

10. Groysman, S.; Segal, S.; Goldberg, I.; Kol, M.; and Goldschmidt, Z. Ta(V) Complexes of a Bulky Amine Tris(phenolate) Ligand: Steric Inhibition vs. Chelate Effect. Inorg. Chem. Commun. 2004, 7, 938-941.

9. Groysman, S.; Goldberg, I.,; Kol, M.; Genizi, E.; and Goldschmidt, Z. Tribenzyl Ta(V) Complexes of Amine Bis(phenolate) Ligands: Investigation of α-Abstraction vs. Ligand Backbone β-Abstraction Paths. Organometallics 2004, 23, 1880-1890.

8. Yeori, A.;  Gendler, S.; Groysman, S.; Goldberg, I.; and Kol. M. Salalen: a Hybrid Salan/Salen Tetradentate [ONNO]–Type Ligand and Its Coordination Behavior with Group IV Metals. Inorg. Chem. Commun. 2004, 7, 280-282.

7. Groysman, S.; Goldberg, I.; Kol, M.; and Goldschmidt Z. Pentabenzyltantalum: Straightforward Synthesis, X-ray Structure and Application in the Synthesis of [O2N]TaBn3-Type and [O3N]TaBn2-Type complexes. Organometallics 2003, 22, 3793-3795.

6. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; and Goldschmidt Z. From THF to Furan: Activity Tuning and Mechanistic Insight via Sidearm Donor Replacement in Group IV Amine Bis(phenolate) Polymerization Catalysts. Organometallics 2003, 22, 3013-3015.

5. Groysman, S.; Tshuva, E. Y.; Reshef, D.; Gendler, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z.; Shuster, M.; and Lidor, G. High-Molecular Weight Atactic Polypropylene prepared by Zirconium Complexes of an Amine Bis(phenolate) Ligand. Isr. J. Chem. 2003, 42, 373-381.

4. Groysman, S.; Goldberg, I.; Kol, M.; Genizi, E.; and Goldschmidt, Z. Group IV complexes of an Amine Bis(phenolate) Ligand Featuring a THF Sidearm Donor: From Highly Active to Living Polymerization Catalysts of 1-Hexene Inorg. Chim. Acta 2003, 345, 137-144. (Protagonists in Chemistry: R. R. Schrock Issue)

3. Bergman, S.; Reshef, D.; Groysman, S.; Goldberg, I.; and Kol, M., Dibenzoeilatin: A Novel Ligand Exhibiting Remarkable Complementary π-π Stacking Interactions. Chem. Commun. 2002, 2374-2375.

2. Groysman, S.; Segal, S.; Shamis, M.; Goldberg, I.;  Kol, M.; Goldschmidt, Z.; and Hayut-Salant, E. Tantalum(V) Complexes of an Amine Triphenolate Ligand: a Dramatic Difference in Reactivity Between Two Labile Positions. J. Chem. Soc., Dalton Trans. 2002, 3425-3426.

1.  Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; and Goldschmidt, Z. [ONXO]-Type Amine Bis(phenolate) Zirconium and Hafnium Complexes as Extremely Active 1-hexene Polymerization Catalysts. Organometallics 2002, 21, 662-670.