Publications

  • P. H. A. Kankanamalage, S. Mazumder, V. Tiwari, K. K. Kpogo, H. B. Schlegel, C. N. Verani “Efficient electro/photocatalytic water reduction using a [NiII(N2Py3)]2+ complex” Chemical Communications 2016, DOI: 10.1039/c6cc06629a
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  • PL. Wickramasinghe, S. Mazumder, C. N. Verani “Modulation of the SOMO/Fermi/LUMO gap in iron(III) surfactants for unimolecular current rectification” Chemistry – A European Journal 2016, 22,10786-10790
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  • S. Gonawala, V. R. Leopoldino, K. Kpogo, C. N. Verani “Langmuir-Blodgett Films of Salophen-based Metallosurfactants as Surface Pretreatment Coatings for Corrosion Mitigation” Chemical Communications 2016, 52,11155-11158
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  • S. Gonawala, H. Baydoun, C. N. Verani “Efficient Water Oxidation Using Langmuir-Blodgett Ultrathin Films of Cobalt-[N2O3] Surfactants on FTO Electrodes” Chemical Communications 2016, 52, 8440-8443
  • D. Li, H. Baydoun, C. N. Verani, S. Brock “Efficient Water Oxidation Using CoMnP Nanoparticles” Journal of the American Chemical Society, 2016, 138, 4006−4009
  • M. Johnson, L. Wickramasinghe, C. N. Verani, R. R. Metzger “Confirmation of the Rectifying Behavior in a Pentacoordinate [N2O2] Iron(III) Surfactant using a Eutectic Ga-In | LB monolayer | Au Assembly” The Journal of Physical Chemistry 2016,120, 3264-3278
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  • D. Basu, S. Mazumder, X. Shi, D. Wanniarachchi, J. Niklas, O. Poluektov, R. Staples, H. B. Schlegel, C. N. Verani “Evaluation of the Mechanistic and Catalytic Behavior of Heteroaxial Cobat(III) Oxime Complexes towards Hydrogen Generation” Chemical Science, 2016 07, 10578−10583
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  • D. Basu, S. Mazumder, X. Shi, R. J. Staples, H. B. Schlegel, C. N. Verani "Distinct Proton and Water Reduction Behavior with a Cobalt(III) Electrocatalyst Based on Pentadentate Oximes" Angewandte Chemie International Edition 2015. 54, 7139-7143.
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  • D. Basu, M. Allard, F. Xavier, M. J. Heeg, H. B. Schlegel, C. N. Verani "Modulation of Electronic and Redox Properties in Phenolate-rich Cobalt(III) Complexes and their Implications for Catalytic Proton Reduction" Dalton Transactions 2015, 44, 3454-3466.
  • D. Basu, S. Mazumder, X. Shi, H. Baydoun, J. Niklas, O. Poluektov, H. B. Schlegel, C. N. Verani "Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine-Rich Environments" Angewandte Chemie International Edition 2015, 54, 2105-2110.
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  • C. N. Verani, J. Driscoll, P. H. Keyes, M. J. Heeg "Cationic Copper(II)-containing Surfactants: Molecular Structures, Film Morphology and Influence on the Alignment of Nematic Mesogens" Inorganic Chemistry 2014, 53, 5647-5655.
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  • L. D. Wickramasinghe, S. Mazumder, S. Gonawala, M. M. Perera, H. Baydoun, B. Thapa, L. Li, L. Xie, G. Mao, Z. Zhou, H. B. Schlegel, C. N. Verani "Mechanisms of Rectification in Au|molecule|Au Devices Based on Langmuir-Blodgett Monolayers of Iron(III) and Copper(II) Surfactants" Angewandte Chemie International Edition 2014, 53, 14462-14467.
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  • D. C. Wanniarachchi, M. J. Heeg, C. N. Verani "Effect of Substituents on the Water Oxidation Activity of [RuII(terpy)(phen)Cl]+ Procatalysts" Inorganic Chemistry 2014, 53, 3311-3319.
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  • D. Tomco, S. Schmitt, M. J. Heeg, Q. P. Dou, C. N. Verani "Inhibition of the 26S Proteasome as a Possible Mechanism for Toxicity of Heavy Metal Species" Journal of Bioinorganic Chemistry 2014, 132, 96-103.
  • N. Farrell, A. Neves, M. Vargas, C. Verani (Guest Editors) "Preface for the JIB Special Issue on Latin American Bioinorganic Chemistry" Journal of Bioinorganic Chemistry 2014, 132, 1.
  • L. D. Wickramasinghe, M. M. Perera, L. Li, G. Mao, Z. Zhou, C. N. Verani "Rectification in Nanoscale Devices Based on an Asymmetric Five-Coordinate Iron(III)/Phenolate Complex" Angewandte Chemie International Edition 2013, 52, 13346-13350.
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  • C. N. Verani, R. Shanmugam, F. R. Xavier, M. M. Allard, K. K. Kpogo "Electronic and interfacial behavior of bimetallic surfactants with copper(II)/pseudohalide cascade cores" Dalton Transactions 2013, 42, 15296-15306.
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  • D. Tomco, F. R. Xavier, C. N. Verani "Probing ligand dissociation in cobalt(III) complexes as a viable mechanism for the inhibition of the 20S Proteasome" Inorganica Chimica Acta 2012, 393, 269-275 (invited article for the special issue "Metals in Medicine" - James Dabrowiak, guest editor).
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  • M. M. Allard, M. J. Heeg, H. B. Schlegel, C. N. Verani "Sequential phenolate oxidation in octahedral cobalt(III) complexes with [N2O3] ligands" European Journal of Inorganic Chemistry 2012,4622-4631 (Invited article for the cluster issue 'Modern coordination chemistry and its impact for meeting global challenges').
  • M. Allard, J. Sonk, M. J. Heeg, B. McGarvey, H. B. Schlegel, C. N. Verani "Bioinspired five-coordinate iron(III) complexes for stabilization of phenoxyl radicals" Angewandte Chemie International Edition 2012, 51, 3178-3182.
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  • C. N. Verani "Probing the inhibition mechanisms of the 26S proteasome by metal complexes in tumorous cells" (Invited review) Journal of Inorganic Biochemistry 2012, 106, 59-67.
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  • M. Frezza, S. Hindo, D. Chen, A. Davenport, S. Schmitt, D. Tomco, C. N. Verani, Q. P. Dou "Metal-based complexes as suitable platforms for anticancer drug design" Encyclopedia of Proteins 2012.
  • F. D. Lesh, R. L. Lord, M. J. Heeg, H. B. Schlegel, C. N. Verani "Unexpected formation of a cobalt(III) phenoxazinylate electron reservoir" (Invited article for the Cluster Issue 'Coopertive & Redox Non-Innocent Ligands in Directing Organometallic Reactivity') European Journal of Inorganic Chemistry 2012, 3, 463-466.
  • D. Tomco, S. Schmitt, B. Ksebati, M. J. Heeg, Q. P. Dou, C. N. Verani "Effects of tethered ligands and of metal oxidation state on the interactions of cobalt complexes with the 26S proteasome" Journal of Inorganic Biochemistry 2011, 105, 1759-1766.
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  • R. Shakya, M. Allard, M. J. Heeg, J. Shearer, B. ,McGarvey, C. N. Verani "Modeling the geometric, electronic, and redox properties of iron(III)-containing amphiphiles with asymmetric [NN'O] headgroups" Inorganic Chemistry 2011, 50, 8356-8366.
  • F. Lesh, M. Allard, R. Shanmugam, L. Hryhorczuk, J. Endicott, H. B. Schlegel, and C. N. Verani "Investigation of the electronic, photosubstitution, redox, and surface properties of new ruthenium(II)-containing amphiphiles" Inorganic Chemistry 2011, 50, 969-977.
  • F. D. Lesh, R. Shanmugam, M. M. Allard, M. Lanznaster, M. J. Heeg, M. T. Rodgers, J. M. Shearer, C. N. Verani "A modular approach to redox-active multimetallic hydrophobes of discoid topology" Inorganic Chemistry 2010, 49, 7226-7228.
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  • C. N. Verani "Films of metal-containing surfactants" The McGraw-Hill Yearbook of Science and Technology 2010, 142-145.
  • S. S. Hindo, R. Shakya, R. Shanmugam, M. J. Heeg, C. N. Verani "Metalloamphiphiles with [Cu2] and [Cu4] headgroups: Syntheses, structures, langmuir films, and effect of subphase changes" European Journal of Inorganic Chemistry 2009, 31, 4686-4694.
  • S. Hindo, M. Frezza, D. Tomco, M. J. Heeg, L. Hryhorczuk, B. R. McGarvey, Q. P. Dou, C. N. Verani "Metals in anticancer therapy: Copper(II) complexes as inhibitors of the 20S proteasome" European Journal of Medicinal Chemistry 2009, 44, 4353-4361.
  • M. Frezza, S. S. Hindo, D. Tomco, M. Allard, Q. C. Cui, M. J. Heeg, D. Chen, Q. P. Dou, C. N. Verani "Comparative activities of nickel(II) and zinc(II) complexes of asymmetric [NN'O] ligands as 26S proteasome inhibitors" Inorganic Chemistry 2009, 48, 5928-5937.
  • H. Jayathilake, J. Driscoll, A. Bordenyuk, L. Wu, S. R. P. da Rocha, C. N. Verani, A.V. Benderskii "Molecular order in Langmuir-Blodgett monolayers of metal-ligand surfactants" Langmuir 2009, 25, 6880-6886.
  • F. D. Lesh; S. S. Hindo, M. M. Allard, P. Jain, B. Peng, L. Hryhorczuk, C. N. Verani "On the effect of coordination and protonation preferences in the amphiphilic behavior of metallosurfactants with asymmetric headgroups" European Journal of Inorganic Chemistry 2009, 345-356.
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  • J. A. Driscoll, M. M. Allard, L. Wu, M. J. Heeg, S. R. P. da Rocha, C. N. Verani "Interfacial behavior and film patterning of redox-active cationic copper(II)-containing surfactants" A European Journal 2008, 14, 9665-9674.
  • J. A. Driscoll, P. H. Keyes, M. J. Heeg, P. A. Heiney, C. N. Verani "Influence of the apical ligand in the thermotropic mesomorphism of cationic copper-based surfactants" Inorganic Chemistry 2008, 47, 7225-7232.
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  • M. Frezza, C. N. Verani, D. Chen, Q. P. Dou "The therapeutic potential of gallium-based complexes in anti-tumor drug design" Letters in Drug Design & Discovery 2007,4, 311-317.
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  • S. S. Hindo, R. Shakya, N. S. Rannulu, M. J. Heeg, M. T. Rodgers, S. R. P. da Rocha, C. N. Verani "Synthesis, redox, and amphiphilic properties of responsive salycilaldimine-copper(II) soft materials" Inorganic Chemistry 2008, 47, 3119-3127.
  • R. Shakya, S. S. Hindo, L. Wu, M. Allard, M. J. Heeg, H. P. Hratchian, B. R. McGarvey, S. R. P. da Rocha, C. N. Verani "Archetypical modeling and amphiphilic behavior of cobalt(II)-containing soft-materials with asymmetric tridentate ligands" Inorganic Chemistry 2007, 46, 9808-9818.
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  • R. Shakya, S. S. Hindo, L. Wu, S. Ni, M. Allard, M. J. Heeg, S. R. P. da Rocha, G. T. Yee, H. P. Hratchian, C. N. Verani "Amphiphilic and magnetic properties of a new class of cluster-bearing [L2Cu44-O)(μ2-carboxylato)4] soft materials" Chemistry, A European Journal 2007, 13, 9848-9956.
  • D. Chen, M. Frezza, R. Shakya, C. Q. Cui, V. Milacic, C. N. Verani, Q. P. Dou "Inhibition of the proteasome activity by gallium(III) complexes contributes to their anti-prostate tumor effects" Cancer Research 2007, 67, 9258-9265.
  • M. Lanznaster, M. J. Heeg, G. T. Yee, B. R. McGarvey, C. N. Verani "Design of molecular scaffolds based on unusual geometries for magnetic modulation of spin-diverse complexes with selective redox response" Inorganic Chemistry 2007, 46, 72-78.
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  • R. Shakya, P. H. Keyes, M. J. Heeg, A. Moussawel, P. A. Heiney, C. N. Verani "Thermotropic mesomorphism of soft materials bearing carboxylate-supported μ4-oxo tetracupric clusters" Inorganic Chemistry 2006, 45, 7587-7589.
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  • R. Shakya, F. Peng, J. Liu, M. J. Heeg, C. N. Verani "Synthesis, structure, and anticancer activity of gallium(III) complexes with asymmetric tridentate ligands: growth inhibition and apoptosis induction of cisplatin-resistant neuroblastoma cells" Inorganic Chemistry 2006, 45, 6263-6268.
  • R. Shakya, C. Imbert, H. P. Hratchian, M. Lanznaster, M. J. Heeg, B. R. McGarvey, M. Allard, H. B. Schlegel, C. N. Verani "Structural, spectroscopic, and electrochemical behavior of trans-phenolato cobalt(III) complexes of asymmetric NN'O ligands as archetypes for metallomesogens" Dalton Transactions 2006, 2517-2525.
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  • M. Lanznaster, H. P. Hratchian, M. J. Heeg, L. Hryhorczuk, B. R. McGarvey, H. B. Schlegel, C. N. Verani "Structural and electronic behavior of unprecedented five-coordinate iron(III) and gallium(III) complexes with a new phenol-rich electroactive ligand" Inorganic Chemistry 2006, 45, 955-957.
  • C. Imbert, H. P. Hratchian, M. Lanznaster, M. J. Heeg, L. Hryhorczuk, B.R. McGarvey, H. B. Schlegel, C. N. Verani "Influence of ligand rigidity and ring substitution on the structural and electronic behavior of trivalent iron and gallium complexes with asymmetric tridentate ligands" Inorganic Chemistry 2005, 44, 7414-7422.
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