Syllabus

The course will consist of one lecture and one hands-on computational lab per week. There will be one midterm and a final (each worth 20%), 6 computational assignments (30%), 4 reviews of papers from the scientific literature (10%) and a major computational project (20%).

Week 1, Jan. 11,13.

Lecture: Potential energy surfaces, Model Chemistries, Asking the right questions (notes)

Lecture: WSU closed due to snow

Week 2, Jan. 18,20.

Lecture: (no class - Martin Luther King Day)

Lecture: Molecular mechanics - theory and practice (notes, Leach - Ch 3; Grant & Richards, Ch. 3)

Week 3, Jan. 25,27.

Comp. Lab: Molecular mechanics calculations with Chem3D

Comp. Lab: Molecular mechanics calculations with Chem3D

Week 4, Feb. 1,3.

Lecture: Introduction to molecular orbital calculations ( notes , Leach - Ch 2; Grant & Richards, Ch. 2, Exploring Chemistry, Appendix A)

Comp. Lab: Intro to Unix; GaussView; Gaussian

Week 5, Feb. 8,10.

Lecture: Equilibrium geometries ( notes, Leach - Ch 4, Exploring Chemistry, Ch 3), molecular vibrations ( notes , Exploring Chemistry, Ch 4)

Comp. Lab: Geometry optimization and vibrational frequency calculations

Week 6, Feb. 15,17.

Lecture: Gaussian output, population analysis (Exploring Chemistry, Ch 2-4)

Comp. Lab: Visualizing orbitals, Calculating molecular properties.

Week 7, Feb. 22,24.

Lecture: Transition states, reaction paths and reaction rates

Comp. Lab: Exploring potential energy surfaces for chemical reactions

Week 8, Mar. 1,3.

Lecture: Post-SCF methods, model chemistries and thermochemistry

Comp. Lab: Internet resources

Week 9, Mar. 8,10.

Lecture: Solvation. Excited states.

Comp. Lab: Continuum models for solvation. Calculating excited states.

Week 10, Mar. 22,24.

Lecture: Midterm.

Comp. Lab: MM/QM calculations.

Week 11, Mar. 29, 31.

Lecture: Gas phase molecular dynamics.

Comp. Lab: Classical trajectory calculations.

Week 12, Apr. 5,7.

Lecture: Macromolecular modeling.

Comp. Lab: Free energy calculations.

Week 13, Apr. 12,14.

Lecture: Simulation of liquids. Car-Parrinello methods

Comp. Lab: Car-Parrinello calculations.

Week 14, Apr. 19,21.

Student presentations of major projects

Apr. 26. Final exam.